English, Article edition: ELECTRONIC AND STRUCTURAL PARAMETERS OF PHOSPHORUSâOXYGEN BONDS IN INORGANIC PHOSPHATE CRYSTALS V. V. ATUCHIN; V. G. KESLER; N. V. PERVUKHINA

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Physical Description
  • article
Language
  • English

Edition details

Title
  • ELECTRONIC AND STRUCTURAL PARAMETERS OF PHOSPHORUSâOXYGEN BONDS IN INORGANIC PHOSPHATE CRYSTALS
Author
  • V. V. ATUCHIN
  • V. G. KESLER
  • N. V. PERVUKHINA
Physical Description
  • article
Notes
  • Wide set of experimental results on binding energy of photoelectrons emitted from P 2p, P 2s, and O 1s core levels has been observed for inorganic phosphate crystals and the parameters were compared using energy differences Î(O 1s - P 2p) and Î (O 1s - P 2s) as most robust characteristics. Linear dependence of the binding energy difference on mean chemical bond length L(PâO) between phosphorus and oxygen atoms has been found. The functions are of the forms: Î (O 1s - P 2p) (eV) =​ 375.54 + 0.146 · L(PâO) (pm) and Î (O 1s - P 2s) (eV) =​ 320.77 + 0.129 · L(PâO) (pm). The dependencies are general for inorganic phosphates and may be used in quantitative component analysis of X-ray photoemission spectra of complex oxide compounds including functional groups with different coordination of P and O atoms.
  • Phosphate, XPS, crystal structure, chemical bonding
  • RePEc:wsi:srlxxx:v:15:y:2008:i:04:p:391-399
Language
  • English
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