2006, 1973, English, Article, Abstract edition: Reaction of atomic oxygen with hydrogen bromide Takacs, Gerald; Glass, G.

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Physical Description
  • 31371 bytes, application/​pdf
  • Abstract
Published
  • The American Chemical Society: Journal of Physical Chemistry
  • 2006-07-19T20:08:13Z
  • 1973-04-26
Language
  • English

Edition details

Title
  • Reaction of atomic oxygen with hydrogen bromide
Author
  • Takacs, Gerald
  • Glass, G.
Published
  • The American Chemical Society: Journal of Physical Chemistry
  • 2006-07-19T20:08:13Z
  • 1973-04-26
Physical Description
  • 31371 bytes, application/​pdf
  • Abstract
Subjects
Notes
  • Article may be found at: http:/​/​pubs3.acs.org/​acs/​journals/​toc.page?incoden=​jpchax&​indecade=​2&​involume=​77&​inissue=​9
  • The reaction of atomic oxygen with HBr was studied in a fast discharge flow system by monitoring epr spectra of O(3P2), Br(2P3/​2), OH(2pi3/​2), and H(2S1/​2) at various reaction times. The experimental results were found to be in accord with the mechanism, O + HBr --> OH + Br (1), OH + HBr --> H2O + Br (2), OH + O + H + O2 (3), H + HBr --> H2 + Br (4), and k1 was measured at 298 K as 4.4 +- 1.0 X 10^-14 cm3 molecule-1 sec-1. The radical intermediate, OH(2pi3/​2), was detected in both the ground state, and in the first vibrationally excited state. Measurements on the relative population of these states allowed a lower limit of 0.3 to be placed on the ratio k(1b)/​k(1a), O + HBr --> OH(v =​ 0) + Br(2P3/​2) (1a) and O + HBr --> OH(v =​ 1) + Br(2P3/​2) (1b).
  • Journal of Physical Chemistry 77N9 (1973) 1182-1186
  • 1520-5215
Language
  • English
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